《中国科学：材料》2022年第6期

Original 中国科学材料中国科学材料 2022-08-29

收录于合集 #《中国科学：材料》2022年目录 9个

Cover Story Feng and co-workers propose a “single-atom site on a chip” strategy for surface-enhanced Raman spectroscopy (SERS), enabling highly sensitive and quantitative Raman detection of multiple analytes. This strategy is realized by modifying monodispersed sites of single tungsten atom oxide on a lead halide perovskite substrate, leading substantial advances in noble-metal-free SERS materials. Ultrahigh enhancement factor and quantitative linear SERS responses are verified using rhodamine, tyrosine and cytosine. The single-atom sites on a chip strategy can also be applied in a portable Raman platform with high sensitivity comparable to that on a benchtop instrument, which can be readily extended to point-of-care testing or in-vitro detection of various biomolecules (see the article on page 1601).

ARTICLE

Oxygen vacancy-expedited ion diffusivity in transition-metal oxides for high-performance lithium-ion batteries

氧空位提高金属氧化物锂离子扩散动力学及储锂性能

Xunlu Wang, Jie Liu, Yifan Hu, Ruguang Ma(马汝广), Jiacheng Wang(王家成)

Sci China Mater, 2022, 65(6): 1421–1430

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Reversible LiOH chemistry in Li-O₂ batteries with free-standing Ag/δ-MnO₂ nanoflower cathode

锂氧电池中基于自支撑Ag/δ-MnO₂纳米花正极的可逆LiOH化学

Linna Dai, Qing Sun, Yuqing Yao, Huanhuan Guo, Xiangkun Nie, Jianwei Li, Pengchao Si, Jingyu Lu(陆敬予), Deping Li(李德平), Lijie Ci(慈立杰)

Sci China Mater, 2022, 65(6): 1431–1442

ARTICLE

Hierarchical Sb₂S₃/SnS₂/C heterostructure with improved performance for sodium-ion batteries

Sb₂S₃/SnS₂/C异质结材料用于高性能钠离子电池

Rui Jia, La Li, Guozhen Shen(沈国震), Di Chen(陈娣)

Sci China Mater, 2022, 65(6): 1443–1452

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MOF-derived three-dimensional ordered porous carbon nanomaterial for efficient alkaline zinc-air batteries

金属有机框架衍生的三维有序多孔碳纳米材料用于高效碱性锌空气电池

Qiuhong Sun, Kai Zhu, Xiangli Ji, Dandan Chen, Cheng Han, Ting-Ting Li, Yue Hu, Shaoming Huang, Jinjie Qian(钱金杰)

Sci China Mater, 2022, 65(6): 1453–1462

ARTICLE

Binder-free S@Ti₃C₂T_x sandwich structure film as a high-capacity cathode for a stable aluminum-sulfur battery

无粘结剂S@Ti₃C₂T_x三明治结构薄膜作为铝硫电池的稳定、高容量正极

Xiao Zheng, Zhilong Wang, Jinjin Li(李金金), Liangming Wei(魏良明)

Sci China Mater, 2022, 65(6): 1463–1475

ARTICLE

Biomimetic brain-like nanostructures for solid polymer electrolytes with fast ion transport

仿生脑状纳米结构的固态聚合物电解质实现快速锂离子输运

Ahmed Eissa Abdelmaoula, Lulu Du, Lin Xu(徐林), Yu Cheng, Amir A. Mahdy, Muhammad Tahir, Ziang Liu, Liqiang Mai(麦立强)

Sci China Mater, 2022, 65(6): 1476–1484

ARTICLE

Tailoring Sr₂Fe_1.5Mo_0.5O_6−δ with Sc as a new single-phase cathode for proton-conducting solid oxide fuel cells

Sc掺杂的Sr₂Fe_1.5Mo_0.5O_6−δ作为质子导体固体氧化物燃料电池的新型单相阴极

Liling Zhang, Yanru Yin, Yangsen Xu, Shoufu Yu, Lei Bi(毕磊)

Sci China Mater, 2022, 65(6): 1485–1494

ARTICLE

Self-assembled carbon nanoribbons with the heteroatom doping used as ultrafast charging cathodes in zinc-ion hybrid supercapacitors

自组装杂原子掺杂碳纳米带作为超快充电锌离子混合超级电容器阴极

Yuying Li, Jiajia Huang(黄佳佳), Liqun Kang, Zhihong Tian, Feili Lai, Dan J.L. Brett, Tianxi Liu, Guanjie He(何冠杰)

Sci China Mater, 2022, 65(6): 1495–1502

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Novel bouquet-like cobalt phosphate as an ultrahigh-rate and durable battery-type cathode material for hybrid supercapacitors

新型花束状磷酸钴作为超高倍率和稳定的混合超级电容器电池型正极材料

Pengcheng Lu, Yifeng Chen, Ruyi Zhou, Chenchen Guo, Xinru Liu, Feifan Yang, Yirong Zhu(朱裔荣)

Sci China Mater, 2022, 65(6): 1503–1511

ARTICLE

Wrapping BiVO₄ with chlorophyll for greatly improved photoelectrochemical performance and stability

叶绿素修饰的钒酸铋对光电化学水分解性能和稳定性的提升

Zunyan Lv, Linxing Meng, Fengren Cao, Liang Li(李亮)

Sci China Mater, 2022, 65(6): 1512–1521

ARTICLE

Electronic modulation of Ni₂P through anion and cation substitution toward highly efficient oxygen evolution

通过阴、阳离子取代调控Ni₂P的电子结构用于高效氧析出反应

Kexin Zhang, Zitao Zhang, Haoming Shen, Yanqun Tang, Zibin Liang, Ruqiang Zou(邹如强)

Sci China Mater, 2022, 65(6): 1522–1530

ARTICLE

Spiral effect of helical carbon nanorods boosting electrocatalysis of oxygen reduction reaction

螺旋碳纳米棒促进电化学氧还原反应性能研究

Peng-Chao Shi, Duan-Hui Si, Ming-Shui Yao, Tao-Tao Liu, Yuan-Biao Huang, Teng Zhang(张腾), Rong Cao(曹荣)

Sci China Mater, 2022, 65(6): 1531–1538

ARTICLE

Dual-strategy of hetero-engineering and cation doping to boost energy-saving hydrogen production via hydrazine-assisted seawater electrolysis

异质工程和阳离子掺杂双重策略促进肼辅助海水电解节能制氢

Qingping Yu, Jingqi Chi, Guishan Liu, Xuanyi Wang, Xiaobin Liu(刘晓斌), Zhenjiang Li, Ying Deng, Xinping Wang, Lei Wang(王磊)

Sci China Mater, 2022, 65(6): 1539–1549

ARTICLE

Construction of a ternary WO₃/CsPbBr₃/ZIF-67 heterostructure for enhanced photocatalytic carbon dioxide reduction

构建三元WO₃/CsPbBr₃/ZIF-67异质结用于高效光催化CO₂还原

Yu-Jie Dong, Yong Jiang, Jin-Feng Liao, Hong-Yan Chen(陈洪燕), Dai-Bin Kuang, Cheng-Yong Su(苏成勇)

Sci China Mater, 2022, 65(6): 1550–1559

ARTICLE

Acidity-dependent self-rolling of graphene oxide nanoscrolls via metal cation-π interaction

酸性环境下金属阳离子-π相互作用驱动氧化石墨烯自卷曲

Ting Shi, Yuan Yao(姚远), Yang Li, Ningning Cao, Jiahuang Jian, Peng Zhang, Songtao Lu, Wei Qin, Xiaohong Wu(吴晓宏)

Sci China Mater, 2022, 65(6): 1560–1568

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Excited-state regulation in eco-friendly ZnSeTe-based quantum dots by cooling engineering

基于冷却工程对环保型 ZnSeTe基量子点的激发态调控

Baoqiang Wu, Shuangyi Zhao, Mingshui Zhang, Zhigao Huang, Chen Chen, Zhigang Zang, Yue Wang(王跃)

Sci China Mater, 2022, 65(6): 1569–1576

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Vapor-solid interfacial reaction and polymerization for wafer-scale uniform and ultrathin two-dimensional organic films

气固界面聚合反应制备晶圆级均匀超薄二维有机薄膜

Wenqian Yao, He Yang, Qingsong Zhang, Longxian Shi, Jianzhe Sun, Yunlong Guo, Lang Jiang, Bin Wu(武斌), Yunqi Liu(刘云圻)

Sci China Mater, 2022, 65(6): 1577–1585

ARTICLE

Large reversible upconversion luminescence modification and 3D optical information storage in femtosecond laser irradiation-subjected photochromic glass

飞秒激光辐照诱导光致变色玻璃中的上转换发光可逆调控和3D光学信息存储

Daiwen Xiao, Xiongjian Huang, Yangke Cun, Zhen Hu, Zan Xu, Xue Bai, Yingzhu Zi, Lixiang Fu, Asif Ali Haider, Jianbei Qiu, Zhiguo Song, Guoping Dong(董国平), Zhengwen Yang(杨正文)

Sci China Mater, 2022, 65(6): 1586–1593

ARTICLE

(C₁₆H₂₈N)₂SbCl₅: A new lead-free zero-dimensional metal-halide hybrid with bright orange emission

(C₁₆H₂₈N)₂SbCl₅: 一种具有亮橙色发射的新型无铅零维金属卤化物杂化物

Hui Peng, Ye Tian, Zongmian Yu, Xinxin Wang, Bao Ke, Yueting Zhao, Tiantian Dong, Jianping Wang(王建平), Bingsuo Zou(邹炳锁)

Sci China Mater, 2022, 65(6): 1594–1600

ARTICLE

Single-atom sites on perovskite chips for record-high sensitivity and quantification in SERS

钙钛矿上单原子位点实现高灵敏定量化表面拉曼增强

Ran Feng, Qing Miao, Xiang Zhang, Peixin Cui, Cong Wang(王聪), Yibo Feng, Liyong Gan, Jiaxing Fu, Shibo Wang, Ziyi Dai, Liming Hu, Yunjing Luo, Weihai Sun, Xiaoxian Zhang, Jiawen Xiao, Jinbo Wu, Bingpu Zhou, Mingqiang Zou, Dawei He, Xiaoyuan Zhou, Xiaodong Han(韩晓东)

Sci China Mater, 2022, 65(6): 1601–1614

ARTICLE

Ferroelectric engineering: Enhanced thermoelectric performance by local structural heterogeneity

铁电工程: 铁电局部结构异质提高热电性能

Xiangyu Meng, Shuo Chen, Haoyang Peng, Hui Bai, Shujun Zhang, Xianli Su, Gangjian Tan, Gustaaf Van Tendeloo, Zhigang Sun, Qingjie Zhang, Xinfeng Tang, Jinsong Wu(吴劲松)

Sci China Mater, 2022, 65(6): 1615–1622

ARTICLE

CMOS-compatible wafer-scale Si subulate array for superb switching uniformity of RRAM with localized nanofilaments

CMOS兼容的晶圆级硅锥阵列局域化细丝形成以实现极佳阻变存储器均一性

Ying Zhang, Xiaolong Zhao(赵晓龙), Xiaolan Ma, Yu Liu, Xuanze Zhou, Meiyun Zhang, Guangwei Xu, Shibing Long

Sci China Mater, 2022, 65(6): 1623–1630

ARTICLE

Memristor based on α-In₂Se₃ for emulating biological synaptic plasticity and learning behavior

基于二维α-In₂Se₃忆阻器的突触可塑性和学习行为

Ying Zhao, Yifei Pei, Zichang Zhang, Xiaoyu Li, Jingjuan Wang, Lei Yan, Hui He, Zhenyu Zhou, Jianhui Zhao, Jingsheng Chen, Xiaobing Yan(闫小兵)

Sci China Mater, 2022, 65(6): 1631–1638

ARTICLE

Control of photocurrent and multi-state memory by polar order engineering in 2H-stacked α-In₂Se₃ ferroelectric

2H α-In₂Se₃铁电体中极序工程控制的光电流和多态存储器

Baohua Lv, Wuhong Xue(薛武红), Zhi Yan, Ruilong Yang, Hao Wu, Peng Wang, Yuying Zhang, Jiani Hou, Wenguang Zhu, Xiaohong Xu(许小红)

Sci China Mater, 2022, 65(6): 1639–1645

ARTICLE

Continuous synthesis of extremely small-sized iron oxide nanoparticles used for T₁-weighted magnetic resonance imaging via a fluidic reactor

采用流体反应器连续制备可用于T₁加权磁共振成像的极小尺寸氧化铁纳米颗粒

Yu Mao, Yan Li, Fengchao Zang, Haoli Yu, Sen Yan, Qingsong Song, Zhiguo Qin, Jianfei Sun, Bo Chen, Xiao Huang(黄晓), Ning Gu(顾宁)

Sci China Mater, 2022, 65(6): 1646–1654

ARTICLE

A SupraGel for efficient production of cell spheroids

一种高效生产细胞球的超分子水凝胶

Sifan Ai, Hui Li, Hao Zheng, Jinming Liu, Jie Gao(高洁), Jianfeng Liu(刘鉴峰), Quan Chen(陈佺),Zhimou Yang(杨志谋)

Sci China Mater, 2022, 65(6): 1655–1661

ARTICLE

The spectrum of building block conformers sustains the biophysical properties of clinically-oriented self-assembling protein nanoparticles

Eric Voltà-Durán, Julieta M Sánchez, Hèctor- López-Laguna, Eloi Parladé, Laura Sánchez-García, Alejandro Sánchez-Chardi, Ario de Marco, Ugutz Unzueta, Esther Vázquez, Antonio Villaverde

Sci China Mater, 2022, 65(6): 1662–1670

ARTICLE

Nano-amorphous–crystalline dual-phase design of Al₈₀Li₅Mg₅Zn₅Cu₅ multicomponent alloy

Al₈₀Li₅Mg₅Zn₅Cu₅多组元合金的纳米非晶-晶态双相设计

Hongzhen Li, Chao Yang, Jianan Fu, Weisi Cai, Yuqiang Yan, Jiang Ma(马将)

Sci China Mater, 2022, 65(6): 1671–1678

ARTICLE

An ultrahigh fatigue resistant liquid crystal elastomer-based material enabled by liquid metal

具有超高抗疲劳性能的液态金属增强型液晶弹性体材料

Hai-Feng Lu, Zhen-Zhou Nie, Hari Krishna Bisoyi, Meng Wang, Shuai Huang, Xu-Man Chen, Zhi-Yang Liu, Hong Yang(杨洪)

Sci China Mater, 2022, 65(6): 1679–1686

ARTICLE